To evaluate the fresh universality of our method, we brought the new ionic bonding get across-connecting to the nonaromatic polymers, then designed a collection of the newest ionic polymers, particularly PAANa, PMANa, and you can PSSNa-co-PMANa (Fig. 5a). Which have chromophore variations, the fresh LRTP emission colors had been successfully updated from purple in order to bluish (Fig. 5b). Such PSSNa polymer, these ionic polymers along with exhibited excitation-centered ultralong phosphorescence below ambient conditions (Fig. 5c and you can Additional Figs. 36–40). The new bluish LRTP band shown an archive life of 1496 ms keeping track of the new emission band from the 450 nm happy by 254 nm. To the better of the degree, it’s the longest longevity of organic phosphorescence within the polymer luminogens (Secondary Fig. 41). Carboxylate (-COO-) acted while the chromophore is actually restricted by ionic connection, thus adding to ultralong phosphorescence of PAANa polymer.

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